Ferromagnetism in the Mott insulator Ba2NaOsO6.

نویسندگان

  • A S Erickson
  • S Misra
  • G J Miller
  • R R Gupta
  • Z Schlesinger
  • W A Harrison
  • J M Kim
  • I R Fisher
چکیده

Results are presented of single crystal structural, thermodynamic, and reflectivity measurements of the double-perovskite Ba2NaOsO6. These characterize the material as a 5d1 ferromagnetic Mott insulator with an ordered moment of approximately 0.2microB per formula unit and TC=6.8(3) K. The magnetic entropy associated with this phase transition is close to Rln2, indicating that the quartet ground state anticipated from consideration of the crystal structure is split, consistent with a scenario in which the ferromagnetism is associated with orbital ordering.

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عنوان ژورنال:
  • Physical review letters

دوره 99 1  شماره 

صفحات  -

تاریخ انتشار 2007